KevinTheJedi
Thanks. I just went with what I found in the Microsoft Info
Go to https://outlook.office.com/mail/
Then click the COG in top right, then "View all Outlook settings" link at the bottom, then "Email" → "Sync email" settings.
This showed me different settings for me, and when I ping them, I get different IP's.
It maybe they're clustered and it doesn't really matter, but thanks anyway. Lots of different answers out there and a lot of head bashing trying to get things working, and fortunately helpful people here.